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Article

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Available under a Creative Commons Attribution Non-Commercial Share Alike 4.0 International Licence

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Molecular Crystals and Liquid Crystals

Abstract

Five orthogonal smectic phases (Sm-A, Sm-Ab, Sm-APR, Sm-APAR, and Sm-APA) were observed in a 4-cyanoresorcinol bisbenzoate with twoterephthalate–based wings achiral bent-core(BC) compound. The phase behavior was investigated by polarising optical microscopy, second harmonic electro-optic response(EO2) and dielectric spectroscopy. The field dependent biaxiality of polar and non-polar Sm-A phases was studied. It is obviously of enormous scientific significance and practical interest to find five different orthogonal smectic phases in a low molecular weight bent-core (BC) compound at relatively low temperatures.

DOI

10.1080/15421406.2015.1025606

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