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Inorganic and nuclear chemistry

Publication Details

Acta Crystallographica Section C Crystal Structure Communications Volume 66, Part 11. November 2010.



The structures of [Cu(AA)6](ClO4)2, (I), and [Mn(AA)6](ClO4)2, (II) (AA is acrylamide, also known as prop-2-enamide; C3H5NO), display both intra- and intermolecular N-H...O hydrogen bonding. A three-dimensional network is propagated via the perchlorate counter-ions. There are two crystallographically independent molecules in the copper complex, with the most significant difference between them being the conformation of one symmetry-related pair of AA ligands which are in the unusual syn conformation. The copper complex exhibits syn/anti disorder of the =CH2 group in one pair of symmetry-related AA ligands. The CuII and MnII centres are both situated on centres of inversion. The copper complex cation has octahedral coordination geometry with typical Jahn-Teller distortions.