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Journal of Physical Chemistry C., Vol.114 (11), 2010, pp.485-4863. DOI: 10.1021/jp911202d Available from the publisher here


Dispersions of as-produced HiPco single-walled carbon nanotubes (SWNTs) in a series of organic solvents were prepared by dilution with the aid of tip sonication. Mild centrifugation (945 g) was carried out to remove large bundles. Atomic force microscopy (AFM) studies revealed that the bundle size decreased as the dispersion was diluted. By measuring the UV−vis−NIR absorption before and after centrifugation as a function of the concentration, the dispersion limit of SWNTs in each solvent can be determined. Correlations between the dispersion limit and solvent solubility parameters, including the Hildebrand solubility parameter and three-dimensional Hansen solubility parameters, are explored, demonstrating that SWNTs are easily dispersed in solvents with Hildebrand solubility parameter range from 22−24 MPa1/2 and Hansen polarity component (δP) 12−14 MPa1/2. No clear correlation between dispersion limits and the dispersion force (δD) or hydrogen bonding force (δH) are evident. It is found, however, that the degree of dispersion depends critically on sample preparation conditions and in particular sonication time. Increased sonication times increase the amount of SWNTs debundled and solubilized but do not appear to affect the dispersion limit. However, increased sonication also induces discernible changes to the SWNTs themselves and in itself influences their solubility, under which conditions no clear solubility parameters can be determined.



Science Foundation Ireland Research Frontiers Program PHY037 2006. Raman instrumentation was funded under the framework of the INSPIRE programme, funded by the Irish Government's Programme for Research in Third Level Institutions, Cycle 4, National Development Plan 2007-2013, supported by the European Union Structural Fund.

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